+
+\pagebreak
+
+\section*{List of Student Achievements}
+
+\pagebreak
+
+\section*{Appendix A - Electron Optics for Total Current Spectroscopy}
+
+
+Figure \ref{electron_gun.pdf} shows the complete electron gun control circuit. The circuit was designed and constructed as part of this project. The design is based upon examples found in \cite{komolov} and \cite{Moore}.
+
+The electron gun has been recycled from a Cathode Ray Oscilloscope. The gun contains a total of 9 electrodes; several electrodes are held at the same potential, as shown in the figure. As shown in figure \ref{electron_gun.pdf}, the electrode potentials are referenced to the cathode, not signal ground; this ensures that the focusing properties of the gun are not affected with changing potential between the cathode and ground.
+
+Here we give a general discussion of aspects of the electron gun:
+\begin{enumerate}
+ \item Cathode
+
+A high yield $\text{Ba}\text{O}^2$ filament was used as the cathode. This type of filament consists of a straight piece of tungsten wire bent at the centre into a sharp kink. A $\text{Ba}\text{O}^2$ disc is attached to the apex of the kink. A heating current (between 1.1 and 1.2A) is applied across the filament. Electrons near the surface of the disc recieve thermal energy as the filament is heated; once an electron has recieved enough energy, it is able to leave the surface of the disc through thermionic emission.
+
+By applying Kirchoff's Laws to the circuit shown in Figure \ref{electron_gun.pdf}, it can be seen that the ammeter labelled ``Emission Current'' measures the total current in all loops passing through an electrode or the sample, and the cathode. This measured current does not include electrons which pass directly through the the vacuum chamber to ground; however, due to the large distance between the gun and the chamber walls, this current can be neglected.
+
+
+ Figure \ref{} shows the measured cathode emission current as a function of time, starting several seconds prior to heating the cathode. From this graph, it can be estimated that at least $10$ minutes should be allowed for the filament to come to thermal equilibrium before commencing measurements.
+
+
+ \item Primary Energy - The potential difference between the sample and the cathode $U$. Primary electrons arriving at the sample have energy $E = eU + \text{constant}$.
+
+ For obvious reasons, it is impractical to directly attach a wire to the emitting surface of the cathode. Instead, two equal resistors are placed in series with the cathode, with the primary energy set point connected to the middle of the resistors. By applying Kirchoff's Voltage Law, making the (reasonable) assumption that both halves of the filament have equal resistance, the potential of the filament tip will be equal to that of the primary energy set point.
+
+
+ \item Wenhault
+
+ The Wenhault is a small cylindrical electrode which surrounds and houses the filament.
+
+ \item Einzel Lens
+
+ \item Deflection Plates
+
+ \item Final Electrode
+\end{enumerate}
+
+As discussed in Section \ref{}, the resolution of total current spectroscopy (and energy resolved secondary electron spectroscopy) is intrinsically linked to the distribution in energies of electrons arriving at the sample. Although the dist
+
+A two dimensional electron gun simulator has also been written in order to help produce figures for qualitative purposes; results of some simulations are shown in Figure \ref{}.
+
+
+
+
+\subsection*{Primary Energy Control and Current Measurement}
+
+In order to collect data on the large number of planned samples for the study, some form of automation was required. The automated system needed to be able to set the primary energy by adjusting the potential of the cathode relative to the sample, and simultaneously record the total current through the sample.
+
+The available power supplies at CAMSP featured analogue inputs for external control. This meant that a Digital to Analogue Convertor (DAC) card was needed to interface between the control computer and the power supply. In addition, the available instruments for current measurement produced analogue outputs. As a result, Analogue to Digital Convertors (ADCs) were required to automate the recording of total current.
+
+Although an external DAC/ADC box was already available for these purposes, initial tests showed that the ADCs on the box did not function. The decision was made to design and construct a custom DAC/ADC box, rather than wait up to two months for a commercial box to arrive. The design of the custom DAC/ADC box is discussed in detail in Appendix B, and the software written for the on-board microprocessor and the controlling computer are included in Appendix D.
+
+Figure \ref{block_diagram.pdf} shows a block diagram including all aspects of the Total Current Spectroscopy experiments. The emission current measurement point was included to allow for monitoring the behaviour of the filament, and confirm the assumptions of constant emission current. After the malfunctioning of one of the two available ammeters, it was only possible to measure sample current. However, earlier tests suggested that for short time periods (several minutes at most) the emission current's dependence upon time was negligable.
+
+\begin{center}
+ \includegraphics[scale=0.80]{figures/block_diagram}
+ \captionof{figure}{Block Diagram for TCS Experiments}
+ \label{block_diagram.pdf}
+\end{center}
+
+
+\begin{landscape}
+
+
+ \includegraphics[scale=0.85]{figures/electron_gun.pdf}
+ \captionof{figure}{Electron Gun and Control Circuit}
+ \label{electron_gun.pdf}
+
+
+\end{landscape}
+
+\section*{Appendix B - DAC/ADC Box - Hardware}
+
+\subsection*{Overview}
+
+In order to automate TCS experiments, both Digital to Analogue and Analogue to Digital Convertors were required (DAC and ADC). To provide these, a custom DAC/ADC Box was designed and constructed. The box can be controlled by any conventional computer with available RS-232 serial communication (COM) ports. Most modern computers no longer feature COM ports; a commercially available convertor can be used to interface between the box's RS-232 output and a standard Universal Serial Bus (USB) port.
+
+
+The key components of the DAC/ADC box hardware include:
+
+\begin{itemize}
+ \item Microprocessor (AVR Butterfly ATMega169)
+ \item Four Analogue to Digital Converter (ADC) inputs
+ \item Single Digital to Analogue Converter (DAC) output (Microchip MCP4922)
+ \item Analogue electronics for amplification at ADC inputs and DAC outputs
+ \item Seperate power supply circuitry for Digital and Analogue electronics
+ \item RS-232 communications for control by a conventional PC or laptop
+\end{itemize}
+
+\subsection*{Microprocessor}
+The DAC/ADC box has been based upon Atmel's AVR Butterfly; an inexpensive and simple demonstration board for the ATMega169 16 Bit microprocessor. The features of the AVR Butterfly include easily accessible ports for Analogue to Digital Convertor (ADC) inputs and digital input/output, an onboard Universal Asynchronous Reciever/Transmitter (USART) for RS-232 serial communications, and a 6 character Liquid Crystal Display (LCD). The AVR Butterfly can be programmed using a conventional computer over the USART using a RS-232 COM port. For modern computers (which do not usually posess COM ports), a RS-232 to USB converter may be used.
+
+Figure \ref{avr_butterfly.pdf} is a labelled photograph of the AVR Butterfly showing the use of the available ports for this project.
+
+
+%Figure of Butterfly
+\begin{center}
+ \includegraphics[scale=0.70]{figures/avr_butterfly.pdf}
+ \captionof{figure}{AVR Butterfly} \label{avr_butterfly.pdf}
+\end{center}
+
+Unless otherwise stated, all voltage differences are specified relative to the power supply ground of the AVR Butterfly.
+
+\subsection*{ADC Inputs}
+
+The AVR Butterfly offers easy access to four of the ATMega169's ADCs through PORTF. Each ADC is capable of measuring voltages of $0 < V_{\text{adc}} < V_{cc}$ with 10 Bit resolution. For measuring voltages outside this range, some circuitry is required between the input voltage and the ADC input. In addition, it is desirable to provide the ADC with some form of input protection against accidental overloading. Figure \ref{adc_normal.pdf} shows the input circuit which was used for three of the four available ADCs.
+
+\begin{center}
+ \includegraphics[scale=0.50]{figures/adc_normal.pdf}
+ \captionof{figure}{ADC4,6,7 Input} \label{adc_normal.pdf}
+\end{center}
+
+
+For making voltage measurements above $V_{cc}$, a voltage divider allows reduction of the voltage at the ADC. By constructing the voltage divider using a variable resistor, the range of measurable inputs could be manually adjusted.
+
+The diodes shown in Figure \ref{adc_normal.pdf} ensure that the ADC is protected from accidental exposure to voltages outside the acceptable range. In normal operation both diodes are off. If $V_{\text{adc}}$ were to become greater than the reference point $V_{cc}$, current would flow between the ADC input and the reference point, acting to reduce $V_{\text{adc}}$ until it reached $V_{cc}$. Similarly, if $V_{\text{adc}}$ fell below ground, current would flow from ground to the ADC input, acting to increase $V_{\text{adc}}$ until it reached ground.
+
+The voltage at the ADC input can be related to the input of the voltage divider using Kirchoff's Voltage Law and Ohm's Law:
+\begin{align*}
+ V_{\text{adc}} &= \frac{R_1}{R_1 + R_2} V_{\text{in}}
+\end{align*}
+Where $V_{\text{in}}$ is the voltage at the input of the circuit, $R_1$ is a fixed resistor, and $R_2$ is variable resistor.
+
+$V_{\text{in}}$ can be therefore be determined from the registered ADC counts by:
+\begin{align*}
+ V_{\text{in}} &= \left(\frac{\text{ADC counts}}{2^{10}}\right) \times \frac{R_1 + R_2}{R_1} V_{cc}
+\end{align*}
+
+\subsubsection*{Differential ADC Input}
+
+During the testing of the TCS experimental apparatus, it became desirable to measure the emission current of the electron gun. The electrometer used for this current measurement was capable of producing an analogue output in the range of $0-1V$. However, the negative terminal of this output was not at ground potential, but rather at the same terminal as the negative input terminal. Directly connecting the electrometer output to one of the ADC inputs discussed above would create a short circuit between the initial energy power supply, and ground (refer to Figures \ref{} and \ref{}). Therefore, it was decided to add a differential stage before the input of one of the ADCs.
+
+Figure \ref{adc5.pdf} shows the modification made to the input for ADC5 on the AVR Butterfly. The original voltage divider and input protection discussed above are still present. The modifications include the addition of an instrumentation amplifier, and low pass filters.
+
+\begin{center}
+ \includegraphics[scale=0.70]{figures/adc5}
+ \captionof{figure}{Differential Input stage for ADC5}
+ \label{adc5.pdf}
+\end{center}
+
+asdfa
+The instrumentation amplifier consists of two stages of operational amplifiers (op-amps); input buffers, and a difference amplifier.
+The difference amplifier can be shown using the ideal op-amp model to produce an output voltage proportional to the difference between its inputs:
+
+\begin{align*}
+ V_{out} &= \frac{R_2}{R_1} \left(V_{2} - V_{1}\right)
+\end{align*}
+
+The two op-amps at the inputs to the differential amplifier are unity gain buffers. Although the outputs of the op amps are equal to their inputs, current is prevented from flowing from the circuit under measurement, and is instead drawn from the op amp power supply.
+
+In principle, two ADC channels could be used to record the positive and negative outputs of the electrometer seperately, with differencing done in software. However this would require modification to the output cable of the electrometer, which may prove inconvenient for future uses.It was decided that the modification of the cable and added complexity of the software required would be more time consuming than differencing the two inputs using the hardware methods described above.
+
+The low pass filters were added to the inputs of ADC5 after it was found that an unacceptable level of AC noise was being output by the electrometer. The level of noise was too high to be filtered in software, for reasons that will be discussed in Appendix D.
+
+\subsection*{Temperature Measurement}
+
+The AVR Butterfly features an onboard thermistor connected to ADC0. Reading ADC0 and applying the formula given in the AVR Butterfly User's Guide \cite{} results in a temperature measurement. This was useful in establishing a link between the changing chamber pressure and the temperature of the laboratory (see Appendix C).
+
+\subsection*{Power Supplies}
+Due to the presence of both analogue and digital electronics in the DAC/ADC box, three seperate supply voltages were required:
+\begin{enumerate}
+ \item Digital logic in the range $3 \to 4.5$V
+ \item Positive op-amp supply in the range $10 \to 15$V
+ \item Negative op-amp supply in the range $-10 \to -15$V
+\end{enumerate}
+
+Circuitry was designed which allowed two seperate single pole power supplies to be used for Digital logic and the op-amps. A dual 0-30V DC power supply has been used for both digital and analogue circuitry.
+
+\subsubsection*{Logic Power Supply}
+The AVR Butterfly runs off $3V < V_{cc} < 4.5V$ DC. Since $V_{cc}$ was also used as the reference voltage for the ADCs and DAC output, it was desirable that $V_{cc}$ be kept constant, despite the absolute level of the power supply. A $3.3V$ voltage regulator has been used for this purpose. The capacitor further smooths the output by shorting high frequency fluctuations to ground.
+
+When the DAC/ADC box was first constructed $V_{cc}$ was supplied by three $1.5V$ batteries. However, due to higher than expected power usage, and the unreliability of the voltage regulator as the input voltage fell below $4V$, inputs for an external power supply were later added.
+
+\begin{center}
+ \includegraphics[scale=0.70]{figures/logic_ps}
+ \captionof{figure}{Logic Power Supply}
+ \label{logic_ps.pdf}
+\end{center}
+
+\subsubsection*{Op-amp Power Supply}
+The DAC/ADC box circuitry involves several operational amplifiers (LF356), which require dual $\pm 10-15V$ supplies. As there were no dual $\pm$ power supplies available, a single $30V$ power supply was used, with the circuit shown in figure \ref{} used to produce $\pm 15V$ relative to ground.
+
+The buffer amplifier ensures that negligable current can flow from the power supply into the logic and ADC circuits, whilst the capacitor removes high frequency fluctuations of the power supply relative to ground.
+
+\subsection*{DAC Output}
+A commercial DAC board was used to produce the DAC output. The Microchip MCP4922 ET-Mini DAC is controlled by the AVR Butterfly using Motorola's Serial Peripheral Interface (SPI) Bus. The software used to implement SPI between the MCP4922 and the AVR Butterfly is discussed in Appendix D.
+
+The ET-Mini DAC can only be powered off $3V$ to $5V$. Using $V_{cc} = 3.3V$ means that the DAC output cannot exceed $V_{cc} = 3.3V$. For TCS, energies of up to $15eV$ are required, so amplification of the DAC output was clearly necessary. A simple non-inverting amplifier with a manually adjustable gain was used to amplify the DAC output by a factor of three. This output was then used to control a laboratory power supply to produce the full range of initial energies.
+
+\subsection*{RS-232 Communications}
+
+The AVR Butterfly features an onboard USART, which can be used both for programming and communication with the ATMega169 processor. The RS-232 communications requires only three wires; Recieve (RX), Transmit (TX) and a common ground.
+
+The requirement that the AVR Butterfly share a common ground with the controlling computer lead to increased noise through ground loops. This is discussed in more detail in Appendix D.
+
+Although the RS-232 is relatively simple to implement, which makes it ideal for non-proprietry microprocessor applications, most modern computers no longer feature RS-232 COM ports. Although a computer with COM ports was available at CAMSP, due to the extreme unreliability of this computer, it was quickly replaced with a laptop that did not possess COM ports, and a commercial RS-232 to USB converter was used to interface with the laptop.
+
+\pagebreak
+
+\section*{Appendix C - Pressure Monitoring}
+
+The pressure in the chamber was monitored by a ion gauge at low pressure (below $10^{-3}$ mbar), and a pirani gauge at high pressure. The gauge included a flurescent Liquid Crystal Display (LCD). In order to automate monitoring of pressure, a USB webcam was placed in front of the gauge LCD. Software was written using the Python Imaging Library (PIL) to convert the image produced by the webcam into a pressure reading. In this way, the pressure could be recorded as a function of time, independent from other measurements performed using the ADC/DAC control box.
+
+Figures \ref{pressure_a.jpg} to \ref{pressure_c.jpg} show the process by which an image taken with the webcam was converted into a pressure reading. The software first identifies bounding rectangles for each individual digit. These are then further subdivided into 7 segments. If enough pixels in a given segment match the colour LCD segments, then the segment can be identified as activated. The software then creates a string corresponding to the activated segments, and looks up the digit in a dictionary.
+
+\begin{center}
+ \includegraphics[scale=0.50]{figures/pressure_a.jpg}
+ \captionof{figure}{An unprocessed image}
+ \label{pressure_a.jpg}
+\end{center}
+
+\begin{center}
+ \includegraphics[scale=0.50]{figures/pressure_c.jpg}
+ \captionof{figure}{Individual digits identified}
+ \label{pressure_b.jpg}
+\end{center}
+
+\begin{center}
+ \includegraphics[scale=0.50]{figures/pressure_d.jpg}
+ \captionof{figure}{Activated segments (green) for a single digit}
+ \label{pressure_c.jpg}
+\end{center}
+
+\section*{Appendix D - Sources of Error}
+
+GROUND LOOOOOOPS!
+
+\section*{Appendix E - Software}
+
+No really, you don't want to know
+
+
+