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%\title{\bf Characterisation of nanostructured thin films}
%\author{Sam Moore\\ School of Physics, University of Western Australia}
%\date{April 2012}
%\maketitle

\begin{center}
        B.Sc. (Hons) Physics Project \par
        {\bf \Large Thesis} \par
        Samuel Moore \\
        School of Physics, University of Western Australia \\
        April 2012
\end{center}
\section*{Characterisation of Nanostructured Thin Films}
{\bf \emph{Keywords:}} surface plasmons, nanostructures, spectroscopy, metallic-blacks \\
{\bf \emph{Supervisers:}} W/Prof. James Williams (UWA), Prof. Sergey Samarin (UWA) \\


%\tableofcontents

\section*{Acknowledgements}

\begin{itemize}
        \item Sergey Samarin
        \item Jim Williams
        \item Paul Guagliardo
        \item Nikita Kostylev
        \item Workshop (for producing electron gun mount?)
        \item Peter Hammond (?)
\end{itemize}

\section{Introduction}
\begin{itemize}
        \item Waffle about motivation for the project
        \begin{itemize}
                \item Metal-Black films may have application for ... something.
                \begin{itemize}
                        \item Radiometer vanes, IR detectors
                        \item Number of applications where high absorbance into IR is required
                        \item These have all been studied before though. 
                \end{itemize}
                \item The electron spectra of metal-blacks have not yet been examined.
                \item Remarkable difference between Metal-Black films (bad vacuum) and normal metal films (UHV)
                \begin{itemize}
                        \item No (detailed/satisfactory) explanation (that I can find...) for difference
                \end{itemize}
                \item Talk about plasmonic based computing? Moore's law? Applications to thin film solar cells?

        \end{itemize}
        \item Specific aims of project
        \begin{enumerate}
                \item Surface density of states / band structure of Black-Au films using TCS (The main aim)
                \item Identification of plasmonic effects in Black-Au films (?) (If they even exist!)
                \begin{itemize}
                        \item Identify plasmonic effects in Au and Ag films with Ellipsometry (this is fairly simple to do)
                \end{itemize}
                \item Combination of Ellipsometry and TCS to characterise thin films (not just Black-Au)
                \begin{itemize}
                        \item Ie: How can one technique be used to support the other?
                \end{itemize}
        \end{enumerate}
        \item Structure of thesis
\end{itemize}

\section{Overview of Theory}
Summarise the literature, refer to past research etc

\subsection{Electron Spectra of Solids and Surface}

\begin{itemize}
        \item Overview of section
\end{itemize}

In this section, we will first introduce the basic concepts needed to describe the electron spectra of solids. A short description of methods for calculating the electron spectra will be given, and the results shown by these calculations. We will then discuss the electron spectra for the near surface region of solids, compared to the ``bulk'' spectra far from the surface.


\subsubsection{Description of Matter in the Solid State}

\begin{itemize}
        \item Define and describe solid geometrically
        \begin{itemize}
                \item Basis + Lattice
                \item Basis groups are assumed to be fixed relative to the lattice
        \end{itemize}
        \item Describe general properties of the potentials seen by electrons in solids
\end{itemize}

In the simplest models, a solid is represented by an infinite crystalline lattice; a geometrically repeated arrangement of some basis group of atoms. The nuclei of atoms are assumed to remain in fixed positions. 

The potential seen by an electron in the lattice is periodic. For a single nuclei, the potential seen by an electron is 

\subsubsection{Calculation of Electron Spectra}

\begin{itemize}
        \item Define electron spectra
        \begin{enumerate}
                \item 
        \end{enumerate}
        \item Free electron gas
        \item Free electron entering a periodic potential
        \item Potentials of real solids
        \item Single vs Multiple electrons
        \item Numerical calculations
        \begin{itemize}
                \item TODO: Actually research this
                \item Find a comparison with a real experimental result
        \end{itemize}
        \item 
\end{itemize}


\subsubsection{The Near-Surface Region}

\begin{itemize}
        \item Real solids have surfaces
        \item Differences between surface region and bulk
        \begin{itemize}
                \item Resulting differences in potential
        \end{itemize}
        \item How the electron spectra may differ from bulk values
        \begin{itemize}
                \item Surface states
                \begin{itemize}
                        \item Tamm \& Shockley States
                \end{itemize}
        \end{itemize}
\end{itemize}

In the preceeding sections, solids were assumed to have infinite spatial extent. In practice, any real solid occupies a finite volume in space. Any interactions between a solid and its environment take place at the surface of the solid. As the volume of the solid is decreased, the role of the surface region in determining the behaviour of the solid in its environment is increased.




\begin{itemize}
        \item Description of the near surface region
        \begin{itemize}
                \item All real solids occupy finite volumes in space.
                \item The surface of a solid is important because interactions between the solid and its surroundings occur in the near surface region.
                \item Characterised physically by:
                \begin{itemize}
                        \item Termination of periodic crystal lattice
                        \item Violation of geometric order
                        \item Distortion of interatomic distances and hence interaction forces
                        \item There is a transition ``near surface'' region between bulk and surface properties, roughly 5 atomic distances. 
                \end{itemize}
                \item Potential seen by an electron at a surface can differ greatly from the bulk
                \item $\implies$ the electron spectra of the near surface region differs from the bulk spectra
                \item Simplest case: Step potential at surface.
                
        \end{itemize}

        \item The Electron Spectra
        \begin{itemize}
                \item Electron Spectra describes the energy eigenstates for an electron in a Bulk or Surface potential
                \item Characterised by 
                \begin{enumerate}
                        \item Energy dispersion $E(\vect{k})$
                        \begin{itemize}
                                \item Dependence of Energy on electron wave vector
                                \item Obtained theoretically by solving Scrhrodinger's Equation
                                \item For a free electron gas, $E = \frac{\hbar^2 k^2}{2m}$
                                \item Periodic potential in bulk solid leads to band gap structure of $E(\vect{k})$
                                \item Periodic potential $\implies$ E is periodic. Only needs to be defined in first Brillouin zone.
                        \end{itemize}
                        \item Density of States $N(E)$
                        \begin{itemize}
                                \item $N(E) = \frac{\Delta N}{\Delta E} = \frac{1}{4\pi^3}\int_S\left(\der{E}{k}\right)^{-1} dS$
                                \item Integral is in momentum space over the isoenergetic surface of energy $E$
                                \item For a free electron gas, $N(E) = $
                        \end{itemize}
                \end{enumerate}
        \end{itemize}

        \item Surface states
        \begin{itemize}
                        \item Simplest model: Step potential
                        \item Two major models  
                \begin{enumerate}
                        \item Tamm States: Periodic potential in solid, free space outside, jump at surface
                        \begin{itemize}
                                \item Energy eigenvalues lie in the forbidden band of the bulk spectra
                                \item Attenuation of eigenvalues from surface to vacuum, oscillation of state within surface
                                \item Max electron density occurs on the crystal surface
                        \end{itemize}
                        \item Shockley states: Potential of surface and bulk cells equal
                        \begin{itemize}
                                \item Corresond to free valences (dangling bonds) at the surface
                        \end{itemize}
                \end{enumerate}
                \item Tamm and Shockley states arise from two extreme models (large change and small change respectively between bulk and surface). In reality, a combination of Tamm and Shockley states appear.
                \item These states arise from termination of the lattice; but the surface cells are assumed undistorted
                \item In reality surface cells are distorted by relaxation and reconstruction of the surface
        \end{itemize}

        \item Main reference: Komolov "Total Current Spectroscopy"
        \item "Solid State Physics" textbooks and "Electron Spectroscopy" textbooks 
\end{itemize}

\subsection{Plasmonics}
I really think I should actually find plasmonic effects before writing too much about them...
\begin{itemize}
        \item Charge density oscillations
        \item Surface and bulk plasmons
        \item Pines and Bohm
        \item Review article from T.W.H Oates et al about using Ellipsometry to characterise plasmonic effects
\end{itemize}

\subsection{Metallic-Black Thin Films}
\begin{itemize}
        \item How they are made (bad vacuum, in air or a noble gas)
        \begin{itemize}
                \item If made in air, there are usually tungsten oxides present (from filament). Refer to paper by Pfund.
        \end{itemize}
        \item Structural difference between Black-Au and ``Shiny'' (need a better term) Au
        \begin{itemize}
                \item Can include electron microscopy images?
                \item An actual photograph of a Black-Au film? Not necessary?
        \end{itemize}
        \item Pfund (earliest publisher, preparation and general properties)
        \item Louis Harris (most research in 50s and 60s)
        \begin{itemize}
                \item L. Harris mostly did transmission spectroscopy in the far infra red (well beyond the ellipsometer and Ocean Optics spectrometer ranges)
                \item The really crappy measurements I did with the Ocean Optics spectrometer seem to agree with these measurements
                \begin{itemize}
                        \item L. Harris' $\lambda$ has a range of 1nm to $100\mu$m; my measurements are only to $1\mu$m
                        \item Agreement in first $1\mu$m anyway
                        \item I should probably re-do those measurements with a less crappy setup, if I actually want to use them
                \end{itemize}
                \item Harris related the optical properties to the structure of the film (condensor strands) via the electronic properties
        \end{itemize}
        \item Plasmonic effects - Deep R. Panjwani (honours thesis)
        \begin{itemize}
                \item Not sure if I can use an honours thesis as a reference.
                \item Concluded that surface plasmon resonance in Black-Au film on solar cells lead to increase in solar cell efficiency
                \item Used simulation that modelled Black-Au film as spherical balls to show E field increased by plasmon resonance
                \begin{itemize}
                        \item Was this model appropriate? Black-Au is more ``smoke'' or ``strand'' like according to other references. Images also do not show ``blob'' like structure.
                \end{itemize}
                \item Need to read this reference more thoroughly
        \end{itemize}
\end{itemize}

\section{Experimental Techniques}

\subsection{Secondary Electron Spectroscopy}

Secondary Electron Spectroscopy encompasses a large group of techniques used for studying the electron spectra of surfaces and solids. In these methods a beam of primary electrons is directed at the surface of a solid. The interactions between primary electrons and the surface give rise to a flux of secondary electrons scattered from the surface. Analysis of this secondary electron flux gives information about the interaction between primary electrons and the surface.

\subsubsection{Electron-Surface Interactions}


\subsubsection{Methods of Secondary Electron Spectroscopy}

Energy-resolved methods of Secondary Electron Spectroscopy are based upon observation of the secondary electron energy distribution at a fixed primary electron energy. The primary electron energy determines which processes are possible, whilst the observed distribution can be related to the probability distribution for the possible processes.

In contrast to Energy-resolved methods, Total Current (or Yield) methods are based on observation of the total current of secondary electrons as a function of primary electron energy. As the primary electron energy is increased, the threshold energies for particular processes are passed. This 

Both Energy-resolved and Total Current methods can be performed 

\subsection{Total Current Secondary Electron Spectroscopy}

Figure \ref{} shows a simplified schematic for the Total Current Spectroscopy experiments conducted during this study. Electrons are emitted from a cathode held at negative potential relative to the target. The electron beam is focused and accelerated onto the target by the electric field of an electron gun. A detector is used to measure the total current passing through the target.

\subsubsection{Electron Optics}

The electron gun used for this experiment was repurposed from an old Cathode-Ray Oscilloscope (CRO). Figure \ref{} shows a simplified diagram of the electron gun, whilst Figure \ref{} shows a photograph of the gun. 



The full circuit diagram for the electron gun control circuit is shown in Appendix A.

\subsubsection{Automatic Data Acquisition}

In order to collect data on the large number of planned samples for the study, some form of automation was required. The automated system needed to be able to incrementally set the initial energy by controlling a power supply, and record the total current measured by an ammeter.

The available power supplies at CAMSP only featured analogue inputs for external control. This meant that a Digital to Analogue Convertor (DAC) card was needed to interface between the control computer and the power supply. In addition, the available instruments for current measurement at CAMSP produced analogue outputs. As a result, Analogue to Digital Convertors (ADCs) would be required to automate the recording of total current.

Although an external DAC/ADC box was already available for these purposes, initial tests showed that the ADCs on the box did not function. The decision was made to design and construct a custom DAC/ADC box, rather than wait up to two months for a commercial box to arrive. The design of the custom DAC/ADC box is discussed in detail in Appendix B, and the software written for the on-board microprocessor and the controlling computer are presented in Appendix C.





\begin{itemize}
        \item Black-Au - 1e-2 mbar vacuum
        \item ``Shiny'' - 1e-6 / 1e-7
        \item Current of ~3.5A through W wire filament spot welded onto Ta strips in turn spot welded to Mo posts
        \item Voltage through filament is ~1 V; quote the power?
        \item Filament isotropically coats sample with desired material.
        \item Possibly get a curve of Au thickness estimated with Ellipsometry vs exposure time?
        \begin{itemize}
                \item Probably too much work and too unreliable
                \item Maybe do it, but only use 2/3 data points
                \item Low priority
        \end{itemize}
\end{itemize}

\subsection{Electron Spectroscopy}

Secondary electron spectroscopy methods are a broad class of methods which investigate surface electron spectra through observing processes in which the surface electrons participate directly \cite{komolov}. 

Total Current Spectroscopy is a group of electron secondary 

\begin{itemize}
        \item 
        \item Total Current Spectroscopy methods measure the total current of secondary electrons as a function of primary electron energy.
        \item These methods are distinguished from ``differential'' methods (such as Auger electron spectroscopy and energy loss spectroscopy) which measure the secondary electron spectrum at a fixed primary electron energy.
        \item 
        \begin{itemize}
                \item Low energy beam of electrons incident on sample
                \item Measure slope of resulting I-V curve
                \item Relate to density of states and electron band structure (Komolov chapter 3.2)
        \end{itemize}
        \item Description of apparatus
        \begin{itemize}
                \item Electron gun and filament
                \item Electron gun control box
                \item ADC/DAC control box and data processing
        \end{itemize}
        \item Photographs vs Diagrams
        \begin{itemize}
                \item Prefer diagrams to photographs
                \item Especially for the ADC/DAC control box circuit. Because it looks like a horrible mess.
        \end{itemize}
\end{itemize}

\subsection{Ellipsometry and Transmission Spectroscopy}
\begin{itemize}
        \item Overview of techniques
        \item Description of apparatus (use VASE manual)
        \item Ocean Optics spectrometer? Usable?
        \item Application of Ellipsometry to finding plasmonic effects
        \begin{itemize}
                \item Surface plasmons = E oscillation parallel to surface $\implies$ only $p$ component of light excites plasmons
        \end{itemize}
\end{itemize}

\section{Experimental Results and Discussion}
\subsection{TCS Measurements}
\begin{itemize}
        \item TCS for Si
        \item TCS for Si + Au
        \item TCS for Si + Black-Au
        \item Affect of preparation pressure on TCS for Si + Black-Au
        \item Repeat for Si + Ag and Si + Black-Ag (?)
\end{itemize}

\subsection{Ellipsometric Measurements}
\begin{itemize}
        \item Ellipsometry to estimate thickness of SiO2 layer on Si
        \item Estimate thickness of Au/Ag on Si+SiO2
        \item Ellipsometric measurements of Si+Black-Au/Ag
        \begin{itemize}
                \item Modelling procedures to characterise Black-Au/Ag
        \end{itemize}
        \item Ellipsometric measurements of Glass+Black-Au/Ag (?)
        \item Transmission spectra of Glass+Black-Au/Ag from earlier in year (?)
\end{itemize}

\section{Achievements}
\begin{itemize}
        \item Deposition of thin films of Au and Black-Au in vacuum chamber
        \item Ellipsometric and spectroscopic measurements on these films
        \item Repurpose vacuum chamber for sample preparation and TCS experiments
        \item Designed and built electronics for TCS experiments
        \begin{itemize}
                \item Electron gun control box
                \item ADC/DAC box
        \end{itemize}
        \item Wrote software for data aquisition and data processing
\end{itemize}

\section{General notes}
\subsection{TCS}
\begin{itemize}
        \item Optimise setup of gun
        \begin{itemize}
                \item Emission current. How much does it vary, why does it vary.
                \item Why does Is/Ie curve shift with successive sweeps? Does sweep modify sample's surface?
                \item Is sample holder acceptable? Are ceramic washers accumulating charge?
                \item How do I tell when the setup is optimised... 
                ``The setup was optimised by looking for an S curve''. Very scientific.
                \item The gun was focused on the phosphor screen... and then I turned it around, changing the distance from the gun to the sample. Brilliant.
        \end{itemize}
        \item Obtain TCS spectra for Si that compares well with literature
        \begin{itemize}
                \item How to relate TCS spectrum to $n(E)$ and $E(\vect{k})$
        \end{itemize}
        \item Prepare Au films, obtain TCS spectra that compares with literature
        \item Obtain TCS spectra of Black-Au films
        \item Use results to compare properties of films with results from other methods in the literature
        \item Uncertainties
        \begin{itemize}
                \item Oscilloscope measurements of inputs to ADC channels under controlled conditions
                \begin{itemize}
                        \item Expected values are +/-3mV due to ADC channel, +/-300mV due to 610B, +/-1mV due to 602
                        \item 610B and 602 will probably be worse because they are ancient
                        \item There is about 200mV of noise between the GND of the ADC box and the electron control box.
                        \item How to reduce ground loops? Not much I can do. Rack is now also grounded to water pipe, but this doesn't seem to make a difference.
                \end{itemize}
                \item Stupid 50Hz AC noise... how to reduce with filters and/or averaging
        \end{itemize}
        \item Create circuit diagrams for Electron gun circuit
        \item Create circuit diagrams for ADC/DAC box
        \begin{itemize}
                \item Simulate behaviour of circuit
                \item Use of instrumentation amplifier on ADC5 to make off-ground measurements
                \item Use of low pass filter on ADC5
        \end{itemize}
        \item Include references to all datasheets, etc
        \item Vacuum chamber
        \begin{itemize}
                \item Base pressure with rotary pump? Was 1e-3 after 30 minutes at start of year, but probably introduced leaks since then
                \item Lowest pressure achieved with turbo pump is 1.1e-7 mbar as of 25/07.
                \item Viton gaskets on some seals. Copper on other.
                \item Flanges:
                \begin{enumerate}
                        \item View window (large, view of sample \& sputtering filaments)
                        \item Rotation manipulator \& sample mount
                        \item Pump inlet
                        \item Filament flanges 1 (used earlier in year, not anymore) and 2
                        \item Inlet with leak valve (for introducing gases into chamber)
                        \item Vent valve on turbo pump
                        \item Electron gun flange
                        \item View window (small, view of back of electron gun)                 
                \end{enumerate}
        \end{itemize}
\end{itemize}

\section*{Appendix A - Electron Gun Control and Current Measurement Circuit}

Figure \ref{} shows the complete electron gun control circuit. The circuit was designed and constructed as part of this project. The design is based upon examples found in \cite{komolov} and \cite{Moore}.

s


\section*{Appendix B - DAC/ADC Box - Hardware}

\subsection*{Overview}

In order to automate TCS experiments, both Digital to Analogue and Analogue to Digital Convertors were required (DAC and ADC). To provide these, a custom DAC/ADC Box was designed and constructed. The box can be controlled by any conventional computer with available RS-232 serial communication (COM) ports. Most modern computers no longer feature COM ports; a commercially available convertor can be used to interface between the box's RS-232 output and a standard Universal Serial Bus (USB) port.


The key components of the DAC/ADC box hardware include:

\begin{itemize}
        \item Microprocessor (AVR Butterfly ATMega169)
        \item Four Analogue to Digital Converter (ADC) inputs
        \item Single Digital to Analogue Converter (DAC) output (Microchip MCP4922)
        \item Analogue electronics for amplification at ADC inputs and DAC outputs
        \item Seperate power supply circuitry for Digital and Analogue electronics
        \item RS-232 communications for control by a conventional PC or laptop
\end{itemize}

\subsection*{Microprocessor}
The DAC/ADC box has been based upon Atmel's AVR Butterfly; an inexpensive and simple demonstration board for the ATMega169 16 Bit microprocessor. The features of the AVR Butterfly include easily accessible ports for Analogue to Digital Convertor (ADC) inputs and digital input/output, an onboard Universal Asynchronous Reciever/Transmitter (USART) for RS-232 serial communications, and a 6 character Liquid Crystal Display (LCD). The AVR Butterfly can be programmed using a conventional computer over the USART using a RS-232 COM port. For modern computers (which do not usually posess COM ports), a RS-232 to USB converter may be used.

Figure \ref{avr_butterfly.pdf} is a labelled photograph of the AVR Butterfly, showing the use of each port in this project.

%Figure of Butterfly
\begin{center}
  \includegraphics[scale=0.50]{figures/atavrbfly.jpg}
\end{center}

Unless otherwise stated, all voltage differences are specified relative to the power supply ground of the AVR Butterfly.

\subsection*{ADC Inputs}

The AVR Butterfly offers easy access to four of the ATMega169's ADCs through PORTF. Each ADC is capable of measuring voltages of $0 < V_{\text{adc}} < V_{cc}$ with 10 Bit resolution. For measuring voltages outside this range, some circuitry is required between the input voltage and the ADC input. In addition, it is desirable to provide the ADC with some form of input protection against accidental overloading.  Figure \ref{adc_normal.pdf} shows the input circuit which was used for three of the four available ADCs. 

\begin{center}
        \includegraphics[scale=0.50]{figures/adc_normal.pdf}
        \captionof{figure}{ADC4,6,7 Input} \label{adc_normal.pdf}
\end{center}


For making voltage measurements above $V_{cc}$, a voltage divider allows reduction of the voltage at the ADC. By constructing the voltage divider using a variable resistor, the range of measurable inputs could be manually adjusted. 

The diodes shown in Figure Figure \ref{fig_ADC_normal} ensure that the ADC is protected from accidental exposure to voltages outside the acceptable range. In normal operation both diodes are off. If $V_{\text{adc}}$ were to become greater than the reference point $V_{cc}$, current would flow between the ADC input and the reference point, acting to reduce $V_{\text{adc}}$ until it reached $V_{cc}$. Similarly, if $V_{\text{adc}}$ fell below ground, current would flow from ground to the ADC input, acting to increase $V_{\text{adc}}$ until it reached ground.

The voltage at the ADC input can be related to the input of the voltage divider using Kirchoff's Voltage Law and Ohm's Law:
\begin{align*}
 V_{\text{adc}} &= \frac{R_1}{R_1 + R_2} V_{\text{in}}
\end{align*}
Where $V_{\text{in}}$ is the voltage at the input of the circuit, $R_1$ is a fixed resistor, and $R_2$ is variable resistor.

$V_{\text{in}}$ can be therefore be determined from the registered ADC counts by:
\begin{align*}
        V_{\text{in}} &= \frac{\text{ADC counts}}{2^{10}} \times \frac{R_1 + R_2}{R_1} V_{cc}
\end{align*}

\subsubsection*{Differential ADC Input}

During the testing of the TCS experimental apparatus, it became desirable to measure the emission current of the electron gun. The electrometer used for this current measurement was capable of producing an analogue output in the range of $0-1V$. However, the negative terminal of this output was not at ground potential, but rather at the same terminal as the negative input terminal. Directly connecting the electrometer output to one of the ADC inputs discussed above would create a short circuit between the initial energy power supply, and ground (refer to Figures \ref{} and \ref{}). Therefore, it was decided to add a differential stage before the input of one of the ADCs.

Figure \ref{} shows the modification made to the input for ADC5 on the AVR Butterfly. The original voltage divider and input protection discussed above are still present. The modifications include the addition of an instrumentation amplifier, and low pass filters.

The instrumentation amplifier consists of two stages of operational amplifiers (op-amps); input buffers, and a difference amplifier.
The difference amplifier can be shown using the ideal op-amp model to produce an output voltage proportional to the difference between its inputs:

\begin{align*}
        V_{out} &= \frac{R_2}{R_1} \left(V_{2} - V_{1}\right)
\end{align*}

The two op-amps at the inputs to the differential amplifier act as unity gain buffers. Although the output of the unity gain buffer is equal to the input on its positive terminal, the buffer prevents current from flowing from the positive terminal to ground. With the buffer amplifiers absent, a current of: would flow between each of the input terminals and ground.

Instrumentation amplifiers are usually constructed in the schematic shown in Figure \ref{}. In this version, the gain of the amplifier can be changed by altering a single resistor. However, more resistors are required. The version actually constructed was designed based upon the small number of resistors available, within a short time frame. Although the design could have later been changed, this would have been of no real benefit, since there was no requirement to adjust the gain of the amplifier.

In principle, two ADC channels could be used to record the positive and negative outputs of the electrometer seperately, with differencing done in software. However this would require modification to the output cable of the electrometer, which may prove inconvenient for future uses.It was decided that the modification of the cable and added complexity of the software required would be more time consuming than differencing the two inputs using the hardware methods described above.

The low pass filters were added to the inputs of ADC5 after it was found that an unacceptable level of AC noise was being output by the electrometer. The level of noise was too high to be filtered in software, for reasons that will be discussed in Appendix D.

\subsection*{Power Supplies}
Due to the presence of both analogue and digital electronics in the DAC/ADC box, three seperate supply voltages were required:
\begin{enumerate}
        \item Digital logic in the range $3 \to 4.5$V
        \item Positive op-amp supply in the range $10 \to 15$V
        \item Negative op-amp supply in the range $-10 \to -15$V
\end{enumerate}

Circuitry was designed which allowed two seperate single pole power supplies to be used for Digital logic and the op-amps. A dual 0-30V DC power supply has been used for both digital and analogue circuitry.

\subsubsection*{Logic Power Supply}
The AVR Butterfly runs off $3V < V_{cc} < 4.5V$ DC. Since $V_{cc}$ was also used as the reference voltage for the ADCs and DAC output, it was desirable that $V_{cc}$ be kept constant, despite the absolute level of the power supply. A $3.3V$ voltage regulator has been used for this purpose. The capacitor further smooths the output by shorting high frequency fluctuations to ground.

When the DAC/ADC box was first constructed $V_{cc}$ was supplied by three $1.5V$ batteries. However, due to higher than expected power usage, and the unreliability of the voltage regulator as the input voltage fell below $4V$, inputs for an external power supply were later added.

\subsubsection*{Op-amp Power Supply}
The DAC/ADC box circuitry involves several operational amplifiers (LF356), which require dual $\pm 10-15V$ supplies. As there were no dual $\pm$ power supplies available, a single $30V$ power supply was used, with the circuit shown in figure \ref{fig_opamp_supply} used to produce $\pm 15V$ relative to ground.

The buffer amplifier ensures that negligable current can flow from the power supply into the logic and ADC circuits, whilst the capacitor removes high frequency fluctuations of the power supply relative to ground.

To simplify circuit diagrams, op-amps will be drawn with the power supply connections ommitted from this point onwards.

\subsection*{DAC Output}
A commercial DAC board was used to produce the DAC output. The Microchip MCP4922 ET-Mini DAC is controlled by the AVR Butterfly using Motorola's Serial Peripheral Interface (SPI) Bus. The software used to implement SPI between the MCP4922 and the AVR Butterfly is discussed in Appendix D.

The ET-Mini DAC can only be powered off $3V$ to $5V$. Using $V_{cc} = 3.3V$ means that the DAC output cannot exceed $V_{cc} = 3.3V$. For TCS, energies of up to $15eV$ are required, so amplification of the DAC output was clearly necessary. A simple non-inverting amplifier with a manually adjustable gain was used to amplify the DAC output by a factor of three. This output was then used to control a laboratory power supply to produce the full range of initial energies.

\subsection*{RS-232 Communications}

The AVR Butterfly features an onboard USART, which can be used both for programming and communication with the ATMega169 processor. The RS-232 communications requires only three wires; Recieve (RX), Transmit (TX) and a common ground. 

The requirement that the AVR Butterfly share a common ground with the controlling computer lead to increased noise through ground loops. This is discussed in more detail in Appendix D.

Although the RS-232 is relatively simple to implement, which makes it ideal for non-proprietry microprocessor applications, most modern computers no longer feature RS-232 COM ports. Although a computer with COM ports was available at CAMSP, due to the extreme unreliability of this computer, it was quickly replaced with a laptop that did not possess COM ports, and a commercial RS-232 to USB converter was used to interface with the laptop.

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